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Library/LaunchDaemons: run in the background as a system process. you, in the former and any user in the latter case) ~/Library/LaunchAgents and /Library/LaunchAgents: run when a user logs on (a specific user, i.e.
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To prevent an application from launching automatically at startup: In addition to this personal location, applications that open automatically can be found-and disabled-in the following locations: Edit Startup Programs using “StartupItems” Folders